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Lithium insertion in copper, indium, tin thiospinels characterized by 119Sn Mössbauer spectroscopy and Rietveld analysis

Identifieur interne : 012E25 ( Main/Repository ); précédent : 012E24; suivant : 012E26

Lithium insertion in copper, indium, tin thiospinels characterized by 119Sn Mössbauer spectroscopy and Rietveld analysis

Auteurs : RBID : Pascal:00-0429420

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Préparation chimique, Insertion, Composé insertion, Lithium, Spinelles, Cuivre sulfure, Indium sulfure, Etain sulfure, Solution solide, Composition chimique, Diffraction RX, Diffraction neutron, Structure cristalline, Spectrométrie Mössbauer, Etain 119, Mécanisme réaction, 6166F, Cu0,5+αIn2,5-3αSn2αS4, Cu In S Sn, Cu In Li S Sn.

English descriptors

KwdEn :
- Chemical composition, Chemical preparation, Copper sulfides, Crystal structure, Experimental study, Indium sulfides, Insertion, Intercalation compounds, Lithium, Moessbauer spectroscopy, Neutron diffraction, Reaction mechanism, Solid solutions, Spinels, Tin 119, Tin sulfides, XRD.

Abstract

Chemical lithium insertion via n-butyllithium was carried out on a family of spinel phases of the Cu₂S-In₂S₃-SnS₂ system, of general formula Cu_0.5+αIn_2.5-3αSn_2αS₄, 0 ≤ α ≤ 0.5. Structural analyses were performed by X-ray and neutron powder diffraction (Rietveld method) and ¹¹⁹Sn Mössbauer spectroscopy. Two mechanisms of lithium insertion occur at the same time. The first is characterized by the reduction of Sn^IV into Sn^II and a spinel to rocksalt transformation. The second leads to the total reduction of tin cations into Sn° and the formation of metallic bonds in an amorphous phase. The relative amounts of indium and tin are discussed with respect to the crystallinity of the rocksalt phase. An electrochemical study was carried out to evaluate the cycling behavior of these compounds, and their possible use as anode material in lithium ion cells.

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Pascal:00-0429420

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Lithium insertion in copper, indium, tin thiospinels characterized by <sup>119</sup>
Sn Mössbauer spectroscopy and Rietveld analysis</title>
<author><name sortKey="Dedryvere, R" uniqKey="Dedryvere R">R. Dedryvere</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (UMR 5072), Université Montpellier II, CC15, Place Eugène Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>France</country>
<placeName><region type="region" nuts="2">Languedoc-Roussillon</region>
<settlement type="city">Montpellier</settlement>
</placeName>
<orgName type="university">Université Montpellier 2</orgName>
</affiliation>
</author>
<author><name sortKey="Olivier Fourcade, J" uniqKey="Olivier Fourcade J">J. Olivier-Fourcade</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (UMR 5072), Université Montpellier II, CC15, Place Eugène Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
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<sZ>2 aut.</sZ>
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<placeName><region type="region" nuts="2">Languedoc-Roussillon</region>
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</author>
<author><name sortKey="Jumas, J C" uniqKey="Jumas J">J. C. Jumas</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (UMR 5072), Université Montpellier II, CC15, Place Eugène Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>France</country>
<placeName><region type="region" nuts="2">Languedoc-Roussillon</region>
<settlement type="city">Montpellier</settlement>
</placeName>
<orgName type="university">Université Montpellier 2</orgName>
</affiliation>
</author>
<author><name sortKey="Denis, S" uniqKey="Denis S">S. Denis</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire de Réactivité et Chimie des Solides (UPRES-A 6007) 33, rue Saint-Leu</s1>
<s2>80039 Amiens</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
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<country>France</country>
<placeName><region type="region" nuts="2">Picardie</region>
<settlement type="city">Amiens</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Perez Vicente, C" uniqKey="Perez Vicente C">C. Perez Vicente</name>
<affiliation wicri:level="2"><inist:fA14 i1="03"><s1>Laboratorio de Química Inorgánica, Facultad de Ciencias, Universidad de Córdoba, Avda, San Alberto Magno s/n</s1>
<s2>14004 Córdoba</s2>
<s3>ESP</s3>
<sZ>5 aut.</sZ>
</inist:fA14>
<country>Espagne</country>
<placeName><region nuts="2" type="communauté">Andalousie</region>
</placeName>
</affiliation>
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<publicationStmt><idno type="inist">00-0429420</idno>
<date when="2000">2000</date>
<idno type="stanalyst">PASCAL 00-0429420 INIST</idno>
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<idno type="wicri:Area/Main/Corpus">012633</idno>
<idno type="wicri:Area/Main/Repository">012E25</idno>
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<seriesStmt><idno type="ISSN">0897-4756</idno>
<title level="j" type="abbreviated">Chem. mater.</title>
<title level="j" type="main">Chemistry of materials</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chemical composition</term>
<term>Chemical preparation</term>
<term>Copper sulfides</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Indium sulfides</term>
<term>Insertion</term>
<term>Intercalation compounds</term>
<term>Lithium</term>
<term>Moessbauer spectroscopy</term>
<term>Neutron diffraction</term>
<term>Reaction mechanism</term>
<term>Solid solutions</term>
<term>Spinels</term>
<term>Tin 119</term>
<term>Tin sulfides</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Préparation chimique</term>
<term>Insertion</term>
<term>Composé insertion</term>
<term>Lithium</term>
<term>Spinelles</term>
<term>Cuivre sulfure</term>
<term>Indium sulfure</term>
<term>Etain sulfure</term>
<term>Solution solide</term>
<term>Composition chimique</term>
<term>Diffraction RX</term>
<term>Diffraction neutron</term>
<term>Structure cristalline</term>
<term>Spectrométrie Mössbauer</term>
<term>Etain 119</term>
<term>Mécanisme réaction</term>
<term>6166F</term>
<term>Cu0,5+αIn2,5-3αSn2αS4</term>
<term>Cu In S Sn</term>
<term>Cu In Li S Sn</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Chemical lithium insertion via n-butyllithium was carried out on a family of spinel phases of the Cu<sub>2</sub>
S-In<sub>2</sub>
S<sub>3</sub>
-SnS<sub>2</sub>
 system, of general formula Cu<sub>0.5+α</sub>
In<sub>2.5-3α</sub>
Sn<sub>2α</sub>
S<sub>4</sub>
, 0 ≤ α ≤ 0.5. Structural analyses were performed by X-ray and neutron powder diffraction (Rietveld method) and <sup>119</sup>
Sn Mössbauer spectroscopy. Two mechanisms of lithium insertion occur at the same time. The first is characterized by the reduction of Sn<sup>IV</sup>
 into Sn<sup>II</sup>
 and a spinel to rocksalt transformation. The second leads to the total reduction of tin cations into Sn° and the formation of metallic bonds in an amorphous phase. The relative amounts of indium and tin are discussed with respect to the crystallinity of the rocksalt phase. An electrochemical study was carried out to evaluate the cycling behavior of these compounds, and their possible use as anode material in lithium ion cells.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>Lithium insertion in copper, indium, tin thiospinels characterized by <sup>119</sup>
Sn Mössbauer spectroscopy and Rietveld analysis</s1>
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<fA11 i1="01" i2="1"><s1>DEDRYVERE (R.)</s1>
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<fA11 i1="02" i2="1"><s1>OLIVIER-FOURCADE (J.)</s1>
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</fA11>
<fA14 i1="01"><s1>Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (UMR 5072), Université Montpellier II, CC15, Place Eugène Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<fA14 i1="02"><s1>Laboratoire de Réactivité et Chimie des Solides (UPRES-A 6007) 33, rue Saint-Leu</s1>
<s2>80039 Amiens</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Laboratorio de Química Inorgánica, Facultad de Ciencias, Universidad de Córdoba, Avda, San Alberto Magno s/n</s1>
<s2>14004 Córdoba</s2>
<s3>ESP</s3>
<sZ>5 aut.</sZ>
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<fC01 i1="01" l="ENG"><s0>Chemical lithium insertion via n-butyllithium was carried out on a family of spinel phases of the Cu<sub>2</sub>
S-In<sub>2</sub>
S<sub>3</sub>
-SnS<sub>2</sub>
 system, of general formula Cu<sub>0.5+α</sub>
In<sub>2.5-3α</sub>
Sn<sub>2α</sub>
S<sub>4</sub>
, 0 ≤ α ≤ 0.5. Structural analyses were performed by X-ray and neutron powder diffraction (Rietveld method) and <sup>119</sup>
Sn Mössbauer spectroscopy. Two mechanisms of lithium insertion occur at the same time. The first is characterized by the reduction of Sn<sup>IV</sup>
 into Sn<sup>II</sup>
 and a spinel to rocksalt transformation. The second leads to the total reduction of tin cations into Sn° and the formation of metallic bonds in an amorphous phase. The relative amounts of indium and tin are discussed with respect to the crystallinity of the rocksalt phase. An electrochemical study was carried out to evaluate the cycling behavior of these compounds, and their possible use as anode material in lithium ion cells.</s0>
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<fC02 i1="01" i2="3"><s0>001B60A66F7</s0>
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<s5>03</s5>
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<fC03 i1="03" i2="X" l="ENG"><s0>Insertion</s0>
<s5>03</s5>
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<s5>04</s5>
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<s5>04</s5>
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<s2>NC</s2>
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<s2>NC</s2>
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<fC03 i1="06" i2="3" l="FRE"><s0>Spinelles</s0>
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<s2>NK</s2>
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<s2>NK</s2>
<s5>10</s5>
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<fC03 i1="08" i2="3" l="ENG"><s0>Indium sulfides</s0>
<s2>NK</s2>
<s5>10</s5>
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<fC03 i1="09" i2="3" l="FRE"><s0>Etain sulfure</s0>
<s2>NK</s2>
<s5>11</s5>
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<s2>NK</s2>
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<s5>12</s5>
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<fC03 i1="10" i2="3" l="ENG"><s0>Solid solutions</s0>
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<s5>13</s5>
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<s5>13</s5>
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<fC03 i1="12" i2="3" l="FRE"><s0>Diffraction RX</s0>
<s5>14</s5>
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<s5>15</s5>
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<fC03 i1="13" i2="3" l="ENG"><s0>Neutron diffraction</s0>
<s5>15</s5>
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<fC03 i1="14" i2="3" l="FRE"><s0>Structure cristalline</s0>
<s5>16</s5>
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<fC03 i1="15" i2="3" l="ENG"><s0>Moessbauer spectroscopy</s0>
<s5>17</s5>
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<fC03 i1="16" i2="3" l="FRE"><s0>Etain 119</s0>
<s5>18</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG"><s0>Tin 119</s0>
<s5>18</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Mécanisme réaction</s0>
<s5>19</s5>
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<fC03 i1="17" i2="X" l="ENG"><s0>Reaction mechanism</s0>
<s5>19</s5>
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<s5>19</s5>
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<fC03 i1="18" i2="3" l="FRE"><s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE"><s0>Cu0,5+αIn2,5-3αSn2αS4</s0>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE"><s0>Cu In S Sn</s0>
<s4>INC</s4>
<s5>93</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE"><s0>Cu In Li S Sn</s0>
<s4>INC</s4>
<s5>94</s5>
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<s5>09</s5>
</fC07>
<fN21><s1>290</s1>
</fN21>
</pA>
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Lithium insertion in copper, indium, tin thiospinels characterized by 119Sn Mössbauer spectroscopy and Rietveld analysis

Lithium insertion in copper, indium, tin thiospinels characterized by 119Sn Mössbauer spectroscopy and Rietveld analysis

Descripteurs français

English descriptors

Abstract

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Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri